Issue 19, 1983
From the journal:

Journal of the Chemical Society, Chemical Communications

Long-range proton hyperfine couplings in radical cations of carbonyl compounds

Larry D. Snow  and  Ffrancon Williams  

Abstract

Large non-aldehydic 1H hyperfine couplings in the radical cations of four carbonyl compounds are assigned to long-range hyperfine interactions relayed through a trans(W-plan) arrangement of C–C and C–H σ bonds; for example, the two strongly coupled hydrogens in the cyclohexanone radical cation are identified by deuterium substitution as the ‘δ’ equatorial pair at C-3 and C-5 rather than the ‘γ’ equatorial pair at C-2 and C-6 assigned previously.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/C39830001090
Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 1090-1092

Permissions

Request permissions

Long-range proton hyperfine couplings in radical cations of carbonyl compounds

L. D. Snow and F. Williams, J. Chem. Soc., Chem. Commun., 1983, 1090 DOI: 10.1039/C39830001090

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements