Issue 4, 1984

Activation of linear and cyclic saturated hydrocarbons involving arene–rhenium compounds: crystal structure of µ-dihydrido-µ-neopentylidene-bis(η-benzene)-dirhenium

Abstract

Co-condensation of rhenium atoms with a mixture of benzene and an alkane, RH = ethane, propane, butane, 2-methylpropane, neopentane, tetramethylsilane, cyclopentane, or cyclohexane gives the compounds [(η-C6H6)Re(η-H)2(η-CR′R″)Re(η-C6H6)], where CR′R″= CHMe, CHEt and CMe2, CHPrn and CMeEt, CH(CHMe2), CHBut, CHSiMe3, cyclopentylidene, or cyclohexdylidene respectively: the crystal structure of the compound where CR′R″= CHBut has been determined.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 240-242

Activation of linear and cyclic saturated hydrocarbons involving arene–rhenium compounds: crystal structure of µ-dihydrido-µ-neopentylidene-bis(η-benzene)-dirhenium

J. A. Bandy, F. G. N. Cloke, M. L. H. Green, D. O'Hare and K. Prout, J. Chem. Soc., Chem. Commun., 1984, 240 DOI: 10.1039/C39840000240

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