Issue 9, 1984

Synthesis and X-ray structure of a cyclopropane precursor alkene–carbene complex of tungsten in which the two functions are parallel

Abstract

Photolysis of pentacarbonyl pent-4-enyl (methoxy)carben tungsten(4) at low temperature affords a new chelated alkene–carbene complex (5) in which, according to an X-ray analysis, the alkene and the carbene functions are parallel, and which decomposes to give the expected cyclopropane (7).

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 574-576

Synthesis and X-ray structure of a cyclopropane precursor alkene–carbene complex of tungsten in which the two functions are parallel

C. A. Toledano, H. Rudler, J. Daran and Y. Jeannin, J. Chem. Soc., Chem. Commun., 1984, 574 DOI: 10.1039/C39840000574

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements