Issue 14, 1984

Highly unsaturated three-bladed propeller molecules. Synthesis and ring inversion dynamics of two [4.4.4]propellatrienetriones

Abstract

The kinetic parameters for antipodal ring inversion were measured for two [4.4.4]propellatrienetriones; the ΔG(298K) values show the incorporation of three–CH[double bond, length half m-dash]CHCO– units does little to increase the barrier and allow for their possible isolation in optically active form.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 942-944

Highly unsaturated three-bladed propeller molecules. Synthesis and ring inversion dynamics of two [4.4.4]propellatrienetriones

H. Jendralla, C. W. Doecke and L. A. Paquette, J. Chem. Soc., Chem. Commun., 1984, 942 DOI: 10.1039/C39840000942

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