Issue 7, 1985

Formation of a specific co-ordination cavity for a chiral amino acid by template synthesis of a polymer Schiff base cobalt(III) complex

Abstract

A template polymer complex, which incorporates N-benzyl-D-valine with almost 100% stereospecificity, was synthesised by copolymerization of Δ-β2-[CO{(R,R)-N,N′-bis[4-(p-vinylbenzyloxy)salicylidene]-1,2-diaminocyclohexane}(N-benzyl-D-valine)](3), styrene, and divinylbenzene, followed by dissociation of the co-ordinated amino acid.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1985, 415-417

Formation of a specific co-ordination cavity for a chiral amino acid by template synthesis of a polymer Schiff base cobalt(III) complex

Y. Fujii, K. Matsutani and K. Kikuchi, J. Chem. Soc., Chem. Commun., 1985, 415 DOI: 10.1039/C39850000415

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