Issue 14, 1985
From the journal:

Journal of the Chemical Society, Chemical Communications

η2-Co-ordination in a 1,3-diphospha-allene complex of platinum(0). Synthesis and solution 31P n.m.r. spectrum of [Pt(PPh3)2(RP[double bond, length half m-dash]C[double bond, length half m-dash]PR)](R = 2,4,6-But3C6H2)

Clara Afiong Akpan,   Mohamed F. Meidine,   John F. Nixon,   Masaaki Yoshifuji,   Kozo Toyota  and  Naoki Inamoto  

Abstract

The first example of a co-ordnation complex containing the novel diphospha-allene ligand RP[double bond, length half m-dash]C[double bond, length half m-dash]PR (R = 2,4,6-But3C6H2) is reported and solution 31P n.m.r. studies indicate that in solution the ligand is bonded in an η2-fashion to the metal as in the isoelectronic allene and CS2(or CO2) complexes.

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Article information

DOI
https://doi.org/10.1039/C39850000946
Article type
Paper

J. Chem. Soc., Chem. Commun., 1985, 946-947

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η2-Co-ordination in a 1,3-diphospha-allene complex of platinum(0). Synthesis and solution 31P n.m.r. spectrum of [Pt(PPh3)2(RP[double bond, length half m-dash]C[double bond, length half m-dash]PR)](R = 2,4,6-But3C6H2)

C. A. Akpan, M. F. Meidine, J. F. Nixon, M. Yoshifuji, K. Toyota and N. Inamoto, J. Chem. Soc., Chem. Commun., 1985, 946 DOI: 10.1039/C39850000946

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