Issue 4, 1986
From the journal:

Journal of the Chemical Society, Chemical Communications

The role of α-hydrogen elimination reactions in the formation of η3-cyclopropenyl-and η4-cyclopentadiene-molybdenum complexes

Frank J. Feher,   Michael Green  and  A. Guy Orpen  

Abstract

Reaction of the Grignard reagents RMgX (R = Me or CH[double bond, length as m-dash]CH2) with [Mo(η2-PhC2Ph){P(OMe)3}2(η-C5H5)][BF4] leads to selective attack on molybdenum and formation of the complexes [MoR(η2-PhC2Ph){P(OMe)3}(η-C5H5)] which undergo thermally promoted α-hydrogen elimination reactions to give η3-cyclopropenyl and η4-cyclopentadiene complexes, the latter being identified by X-ray crystallography.

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Article information

DOI
https://doi.org/10.1039/C39860000291
Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 291-293

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The role of α-hydrogen elimination reactions in the formation of η3-cyclopropenyl-and η4-cyclopentadiene-molybdenum complexes

F. J. Feher, M. Green and A. G. Orpen, J. Chem. Soc., Chem. Commun., 1986, 291 DOI: 10.1039/C39860000291

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