Issue 24, 1986
From the journal:

Journal of the Chemical Society, Chemical Communications

Organometallic clusters containing oxygen atoms: (η-C5H5)5(O)V6(µ3-O)8 and {(η-C5H5)5V6(µ-3-O)8}2(µ-O), two further derivatives of octahedral (η-C5H5)6V6(µ3-O)8

Frank Bottomley,   Daniel F. Drummond,   Daniel E. Paez  and  Peter S. White  

Abstract

Oxidation of (η-C5H5)2V with C5H5NO in toluene gives (η-C5H5)4V4(µ3-O)4 and (η-C5H5)5(O)V6(µ3-O)8(1) whereas oxidation with Me3NO gives {(η-C5H5)5V6(µ3-O)8}2{(µ-O)2V(η-C5H5)(NMe3)2} and {(η-C5H5)5V6(µ3-O)8}2(µ-O)(2); the structures of (1) and (2) have been established by X-ray crystallography.

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Article information

DOI
https://doi.org/10.1039/C39860001752
Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 1752-1753

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Organometallic clusters containing oxygen atoms: (η-C5H5)5(O)V6(µ3-O)8 and {(η-C5H5)5V6(µ-3-O)8}2(µ-O), two further derivatives of octahedral (η-C5H5)6V6(µ3-O)8

F. Bottomley, D. F. Drummond, D. E. Paez and P. S. White, J. Chem. Soc., Chem. Commun., 1986, 1752 DOI: 10.1039/C39860001752

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