Issue 2, 1987

Stabilisation of trivalent platinum by structurally accommodating thiamacrocycles

Abstract

The complex cation [Pt(1)2]2+[(1)= 1,4,7-trithiacyclononane] shows a quasi square based pyramidal structure with one non-bonding sulphur donor atom; electrochemical oxidation at +0.5 V. vs. Fc0/Fc+(Fc = ferrocene) at 20 °C in MeCN affords a paramagnetic platinum(III) species.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 118-120

Stabilisation of trivalent platinum by structurally accommodating thiamacrocycles

A. J. Blake, R. O. Gould, A. J. Holder, T. I. Hyde, A. J. Lavery, M. O. Odulate and M. Schröder, J. Chem. Soc., Chem. Commun., 1987, 118 DOI: 10.1039/C39870000118

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