SCHEDULED MAINTENANCE
cis-RhCl(CO)2Ph2P(CH2)2P(O) Ph2, the only species observed during catalysis, formed from cis-[graphic omitted])Ph2 and CO, is the sole active species observed during catalytic studies and results in the carbonylation of methanol with catalyst turnover frequencies approaching 400 h–1 at 80 °C and 50 psig CO; the crystal structure of the analogue cis-[graphic omitted])Ph2 is reported.
R. W. Wegman, A. G. Abatjoglou and A. M. Harrison, J. Chem. Soc., Chem. Commun., 1987, 1891 DOI: 10.1039/C39870001891
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