Issue 10, 1988
From the journal:

Journal of the Chemical Society, Chemical Communications

Model of the SN2 nucleophilic substitution at the Si atom: X-ray structural study of N-(halogenodimethylsilylmethyl) lactams

A. A. Macharashvili,   V. E. Shklover,   Yu. T. Struchkov,   G. I. Oleneva,   E. P. Kramarova,   A. G. Shipov  and  Yu. I. Baukov  

Abstract

X-ray studies show that Si–O and Si–X (X = I, Br, Cl, F) distances at the pentaco-ordinated Si atom in N-(halogenodimethylsilylmethyl)lactams vary over a wide range [1.749(2)–2.461(8) and 3.734(1)–1.630(7)Å, respectively] in the series X = I → Br → Cl → F; hence these compounds can be regarded as models of intermediate stages of SN2 substitution at the tetrahedral Si atom.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/C39880000683
Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 683-685

Permissions

Request permissions

Model of the SN2 nucleophilic substitution at the Si atom: X-ray structural study of N-(halogenodimethylsilylmethyl) lactams

A. A. Macharashvili, V. E. Shklover, Yu. T. Struchkov, G. I. Oleneva, E. P. Kramarova, A. G. Shipov and Yu. I. Baukov, J. Chem. Soc., Chem. Commun., 1988, 683 DOI: 10.1039/C39880000683

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements