Issue 18, 1989
From the journal:

Journal of the Chemical Society, Chemical Communications

Oxidative addition of aryl–halogen bonds to platinum(II) and the structure of a complex formed by aryl–fluoride oxidative addition

Craig M. Anderson,   Richard J. Puddephatt,   George Ferguson  and  Alan J. Lough  

Abstract

The complexes [PtMe2(Me2NCH2CH2N[double bond, length as m-dash]CHAr)] react by oxidative addition of the aryl–halogen bond when Ar = 2-BrC6H4, 2-CIC6H4, or C6F5 but by ortho-metallation when Ar = 2-FC6H4 or C6H5, and in the case where Ar = C6F5, the oxidative addition product adds acetone across the imine bond and the complex formed has been characterized crystallographically as a hydrogen-bonded dimer; the reactivity to oxidative addition can be correlated with the C–X bond energy.

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Article information

DOI
https://doi.org/10.1039/C39890001297
Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 1297-1298

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Oxidative addition of aryl–halogen bonds to platinum(II) and the structure of a complex formed by aryl–fluoride oxidative addition

C. M. Anderson, R. J. Puddephatt, G. Ferguson and A. J. Lough, J. Chem. Soc., Chem. Commun., 1989, 1297 DOI: 10.1039/C39890001297

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