Issue 22, 1990

Polyhedral oligometallasilasesquioxanes as models for silica-supported catalysts: chromium attached to two vicinal siloxy groups

Abstract

The reaction of [(cyclo-C6H11)7Si7O9(OSiMe3)(OH)2] with CrO3 leads to the formation of [(cyclo-C6H11)7Si7O11(OSiMe3)CrO2], a new crystallographically characterized silyl-chromate complex that catalyses the polymerization of ethylene in the presence of trialkylaluminium reagents.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 1614-1616

Polyhedral oligometallasilasesquioxanes as models for silica-supported catalysts: chromium attached to two vicinal siloxy groups

F. J. Feher and R. L. Blanski, J. Chem. Soc., Chem. Commun., 1990, 1614 DOI: 10.1039/C39900001614

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements