Issue 3, 1991
From the journal:

Journal of the Chemical Society, Chemical Communications

Comparison of the X-ray crystal structures of the sodium and potassium 2,4,6-tris(trifluoromethyl)phenoxides (RO–) and 2,4,6-tris(trifluoromethyl)benzenethiolates (RS–); [Na(OR)(thf)2]2, [K(OR)(thf)2(µ-thf)]2, [Na(SR)(thf)2·0.25thf]x and [K(SR)(thf)]x(thf = tetrahydrofuran)

Sally Brooker,   Frank T. Edelmann,   Thomas Kottke,   Herbert W. Roesky,   George M. Sheldrick,   Dietmar Stalke  and  Kenton H. Whitmire  

Abstract

[Na(OR)(thf)2]21, [K(OR)(thf)2(µ-thf)]22, [Na(SR)(thf)2·0.25thf]x3 and [K(SR)-(thf)]x4 were formed by the reaction of the appropriate combinations of 2,4,6-tris(trifluoromethyl)phenol (ROH) or 2,4,6-tris(trifluorornethyl)benzenethiol (RSH) with NaH or KH; compounds 1-4 have been characterised by NMR spectrosccpy and single crystal X-ray structure analysis, both phenoxides being dimeric whereas two distinct polymeric structural types are observed for the thiolates.

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Article information

DOI
https://doi.org/10.1039/C39910000144
Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 144-146

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Comparison of the X-ray crystal structures of the sodium and potassium 2,4,6-tris(trifluoromethyl)phenoxides (RO–) and 2,4,6-tris(trifluoromethyl)benzenethiolates (RS–); [Na(OR)(thf)2]2, [K(OR)(thf)2(µ-thf)]2, [Na(SR)(thf)2·0.25thf]x and [K(SR)(thf)]x(thf = tetrahydrofuran)

S. Brooker, F. T. Edelmann, T. Kottke, H. W. Roesky, G. M. Sheldrick, D. Stalke and K. H. Whitmire, J. Chem. Soc., Chem. Commun., 1991, 144 DOI: 10.1039/C39910000144

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