Issue 19, 1991

Two new ten-vertex arachno mixed-atom diheteroboranes, 6,9-CNB8H13 and 6,9-CSB8H12

Abstract

Treatment of the monocarbaborane arachno-4-CB8H14 with either sodium nitrite or elemental sulphur in the presence of triethylamine results in the isolation of two representatives of the ten-vertex arachno family of cluster carbaheteroboranes, 6,9-CNB8H13 and 6,9-CSB8H12, the constitution of which has been established on the basis of 1H, 11B, [11B–11B]-COSY, and [1H–1H]-COSY NMR data and mass spectroscopic measurements.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 1389-1390

Two new ten-vertex arachno mixed-atom diheteroboranes, 6,9-CNB8H13 and 6,9-CSB8H12

J. Holub, T. Jelínek, J. Plešek, B. Štíbr, S. Heřmánek and J. D. Kennedy, J. Chem. Soc., Chem. Commun., 1991, 1389 DOI: 10.1039/C39910001389

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