SCHEDULED MAINTENANCE
The reactions of acrylic acid with various of difluoroalkanoyl peroxides {(RfCO2)2, Rf= C3F7, C6F13 CF(CF3)[OCF2CF(CF3)]mOC3F7, m= 0, 1, 2} have been found to give new fluoroalkylated oligomers containing carboxy groups {Rf[CH2CH(CO2H]nRf} under mild conditions, and these compounds are able to reduce the surface tension of water to 10 mN m–1 levels.
H. Sawada, Y. Gong, Y. Minoshima, T. Matsumoto, M. Nakayama, M. Kosugi and T. Migita, J. Chem. Soc., Chem. Commun., 1992, 537 DOI: 10.1039/C39920000537
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