Issue 2, 1993
From the journal:

Journal of the Chemical Society, Chemical Communications

The isolation and X-ray structure determination of an active intermediate in the accelerated sulfur vulcanization of alkenes

Peter Versloot,   Martin van Duin,   Jaap G. Haasnoot,   Jan Reedijk  and  Anthony L. Spek  

Abstract

In the sulfur vulcanization reaction of 2,3-dimethylbut-2-ene(C6H12), in the presence of S8, ZnO and organic accelerators, intermediate products are formed with consist of an alkene bound by sulfur to an accelerator fragment: C6H11–Sn–S(S)CNMe2, where n[gt-or-equal] 0; the isolation characterisation and vulcanization activity of 2,3-dimethylbut-2-en-1-yl dimethyltrithiopercarbamate [C6H11–S–S(S)CNMe2] is described.

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Article information

DOI
https://doi.org/10.1039/C39930000183
Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 183-184

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The isolation and X-ray structure determination of an active intermediate in the accelerated sulfur vulcanization of alkenes

P. Versloot, M. van Duin, J. G. Haasnoot, J. Reedijk and A. L. Spek, J. Chem. Soc., Chem. Commun., 1993, 183 DOI: 10.1039/C39930000183

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