Issue 2, 1993

A novel synthetic metal catalytic system for dehydrogenative oxidation based on redox of polyaniline

Abstract

Polyaniline serves as a synthetic metal catalyst with reversible redox under oxygen to induce dehydrogenative and/or decarboxylative oxidation of benzylamines and 2-phenylglycine into the corresponding imines and, in combination with copper(II) chloride or iron(III) chloride, dehydrogenation of cinnamyl alcohol into cinnamaldehyde possibly due to complexation.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 194-195

A novel synthetic metal catalytic system for dehydrogenative oxidation based on redox of polyaniline

T. Hirao, M. Higuchi, I. Ikeda and Y. Ohshiro, J. Chem. Soc., Chem. Commun., 1993, 194 DOI: 10.1039/C39930000194

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