Issue 13, 1993
From the journal:

Journal of the Chemical Society, Chemical Communications

Interconversion of auI/II/III centres in thioether macrocyclic complexes: the synthesis, structures and redox properties of [Au([18]aneS6)]PF6 and [Au2([15]aneS5)2][B(C6F5)4]2

Alexander J. Blake,   Anne Taylor  and  Martin Schröder  

Abstract

The interconversion of mononuclear AuI/II/III centres in thioether macrocyclic complexes is related to the stereochemical properties of the parent AuI species; the structure of [Au([18]aneS6)]+ shows a distorted tetrahedral [2 + 2] coordination at AuI, while the AuI complex of [15]aneS5 is binuclear with AuI ions bridging [15]aneS5 ligands in a macrobicyclic structure.

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Article information

DOI
https://doi.org/10.1039/C39930001097
Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 1097-1098

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Interconversion of auI/II/III centres in thioether macrocyclic complexes: the synthesis, structures and redox properties of [Au([18]aneS6)]PF6 and [Au2([15]aneS5)2][B(C6F5)4]2

A. J. Blake, A. Taylor and M. Schröder, J. Chem. Soc., Chem. Commun., 1993, 1097 DOI: 10.1039/C39930001097

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