Several oxometal species including MnO4–, Cr2O72–, CrO3Cl–, RuO4–, RuO2Cl3– and [Ru(TMC)O2]2+(TMC = 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane) have been studied by electrospray tandem mass spectrometry; in each case the mass spectrum obtained from solution in acetonitrile shows the molecular ion as the base peak with a minimal degree of fragmentation.
T. Lau, J. Wang, K. W. M. Siu and R. Guevremont, J. Chem. Soc., Chem. Commun., 1994, 1487 DOI: 10.1039/C39940001487
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