Issue 2, 1995
From the journal:

Journal of the Chemical Society, Chemical Communications

Intermolecular C–H activation by reactive titanocene alkylidene intermediates

Harry van der Heijden  and  Bart Hessen  

Abstract

Thermal α-H abstraction from (C5H4R)2Ti(CH2CMe3)2(R = H, Me) produces reactive titanocene neopentylidene intermediates under mild conditions, that can either be trapped with PMe3 to yield the alkylidene complexes (C5H4R)2Ti(CHCMe3)PMe3, or add C–H bonds of hydrocarbon substrates R′H (R′H = benzene, p-xylene) to the Ti[double bond, length half m-dash]C double bond to produce (C5H4R)2Ti(CH2CMe3)R′; an alternative reaction pathway, insertion of the alkylidene moiety into the cyclopentadienyl C–C bond, has been observed in the presence of THF.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/C39950000145
Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 145-146

Permissions

Request permissions

Intermolecular C–H activation by reactive titanocene alkylidene intermediates

H. van der Heijden and B. Hessen, J. Chem. Soc., Chem. Commun., 1995, 145 DOI: 10.1039/C39950000145

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements