The TS-1/H2O2 system efficiently catalyses the hydroxy-assisted chemoselective epoxidation of α-hydroxyalkene in geraniol, and the stereoselective epoxidation of cyclopent-2-en-1-ol/cyclohex-2-en-1-ol producing the epoxide which is cis to OH with high selectivity (90:10 cis: trans).
R. Kumar, G. C. G. Pais, B. Pandey and P. Kumar, J. Chem. Soc., Chem. Commun., 1995, 1315 DOI: 10.1039/C39950001315
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