Issue 24, 2013

New donor–π–acceptor sensitizers containing 5H-[1,2,5]thiadiazolo [3,4-f]isoindole-5,7(6H)-dione and 6H-pyrrolo[3,4-g]quinoxaline-6,8(7H)-dione units

Abstract

Two new D–π–A sensitizers (L101 and L102) incorporating 5H-[1,2,5]thiadiazolo [3,4-f]isoindole-5,7(6H)-dione and 6H-pyrrolo[3,4-g]quinoxaline-6,8(7H)-dione core structures were synthesized and tested in liquid dye-sensitized solar cells (DSCs). L102 achieved a promising power conversion efficiency (PCE) of 6.2% (AM 1.5, 100 mW cm−2).

Graphical abstract: New donor–π–acceptor sensitizers containing 5H-[1,2,5]thiadiazolo [3,4-f]isoindole-5,7(6H)-dione and 6H-pyrrolo[3,4-g]quinoxaline-6,8(7H)-dione units

Supplementary files

Article information

Article type
Communication
Submitted
04 Jan 2013
Accepted
28 Jan 2013
First published
29 Jan 2013

Chem. Commun., 2013,49, 2409-2411

New donor–π–acceptor sensitizers containing 5H-[1,2,5]thiadiazolo [3,4-f]isoindole-5,7(6H)-dione and 6H-pyrrolo[3,4-g]quinoxaline-6,8(7H)-dione units

H. Li, T. M. Koh, A. Hagfeldt, M. Grätzel, S. G. Mhaisalkar and A. C. Grimsdale, Chem. Commun., 2013, 49, 2409 DOI: 10.1039/C3CC00060E

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