Issue 36, 2013
From the journal:

Dalton Transactions

Heterotrimetallic complexes of a phenylene-bridged tricarbene ligand†

Ramananda Maity,a   Christian Schulte to Brinkea  and  F. Ekkehardt Hahn*a  

* Corresponding authors

a Institut für Anorganische und Analytische Chemie and NRW Graduate School of Chemistry, Westfälische Wilhelms-Universität Münster, Corrensstraße 30, D-48149 Münster, Germany
E-mail: fehahn@uni-muenster.de
Fax: +49-251-8333108

Abstract

Reaction of the benzene-1,3,5-trisimidazolium salt H3-1(Br)3 with [Rh(Cp*)(Cl)2]2 results in the formation of the dinuclear, doubly orthometalated complex [2]Br, which yields, depending on the metal source provided, either a triply orthometalated heterotrimetallic Rh2/Ir complex [3] or trinuclear heterotrimetallic Rh2/Au complexes of types [4a] or [4b].

Graphical abstract: Heterotrimetallic complexes of a phenylene-bridged tricarbene ligand

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Article information

DOI
https://doi.org/10.1039/C3DT51572A
Article type
Communication
Submitted
13 Jun 2013
Accepted
12 Jul 2013
First published
15 Jul 2013

Dalton Trans., 2013,42, 12857-12860

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Heterotrimetallic complexes of a phenylene-bridged tricarbene ligand

R. Maity, C. Schulte to Brinke and F. E. Hahn, Dalton Trans., 2013, 42, 12857 DOI: 10.1039/C3DT51572A

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