Issue 33, 2014

Effect of Al2O3 coverage on SiC particles for electrically insulated polymer composites with high thermal conductivity

Abstract

Al2O3-covered SiC/epoxy composites were prepared using a simple sol–gel method. The results of FE-SEM, TGA, and XPS indicated that the surfaces of the SiC particles had a large, dense, and homogenous distribution of Al2O3. It was found that the introduction of Al2O3 on the SiC surface improved the interfacial adhesion between the epoxy matrix and SiC particles; this resulted in an increase in the thermal conductivity of the composites since the thermal boundary resistance at the filler–matrix interface was decreased. In addition, Al2O3-covered SiC composites showed decreased electrical conductivity owing to decreased electron tunneling compared with raw SiC composites. Thus, the Al2O3-covered SiC composites prepared in the present work could prove to be desirable polymer composites to be used as thermal interface materials that are employed in the electronics industry.

Graphical abstract: Effect of Al2O3 coverage on SiC particles for electrically insulated polymer composites with high thermal conductivity

Article information

Article type
Paper
Submitted
17 Feb 2014
Accepted
26 Mar 2014
First published
28 Mar 2014

RSC Adv., 2014,4, 17015-17021

Effect of Al2O3 coverage on SiC particles for electrically insulated polymer composites with high thermal conductivity

Y. Hwang, M. Kim and J. Kim, RSC Adv., 2014, 4, 17015 DOI: 10.1039/C4RA01382D

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