Issue 31, 2015
From the journal:

RSC Advances

Proline-functionalized chitosan–palladium(ii) complex, a novel nanocatalyst for C–C bond formation in water†

A. R. Hajipour,*ab   E. Boostania  and  F. Mohammadsaleha  

* Corresponding authors

a Pharmaceutical Research Laboratory, Department of Chemistry, Isfahan University of Technology, Isfahan 84156, Islamic Republic of Iran
E-mail: haji@cc.iut.ac.ir
Fax: +98 313 391 2350
Tel: +98 313 391 3262

b Department of Pharmacology, University of Wisconsin, Medical School, 1300 University Avenue, Madison, WI, USA

Abstract

An environmentally friendly palladium-based catalyst supported on proline-functionalized chitosan was successfully prepared and evaluated as a heterogeneous nanocatalyst in the Suzuki cross-coupling reaction of various aryl halides with phenylboronic acid. The catalyst was characterized by FT-IR, FE-SEM, TEM, XRD, SEM-EDX, ICP and TGA techniques and exhibited reasonable catalytic activity in the reaction system, producing substituted biaryls in good to excellent yields. In addition, the catalyst could be recovered in a facile manner from the reaction mixture and recycled several times.

Graphical abstract: Proline-functionalized chitosan–palladium(ii) complex, a novel nanocatalyst for C–C bond formation in water

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Article information

DOI
https://doi.org/10.1039/C5RA01187F
Article type
Paper
Submitted
20 Jan 2015
Accepted
26 Feb 2015
First published
26 Feb 2015

RSC Adv., 2015,5, 24742-24748

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Proline-functionalized chitosan–palladium(II) complex, a novel nanocatalyst for C–C bond formation in water

A. R. Hajipour, E. Boostani and F. Mohammadsaleh, RSC Adv., 2015, 5, 24742 DOI: 10.1039/C5RA01187F

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