Issue 44, 2016
From the journal:

Dalton Transactions

Palladacycle catalysis: an innovation to the Suzuki–Miyaura cross-coupling reaction†

Fátima Lucio-Martínez,a   Luis A. Adrio,a   Paula Polo-Ces,a   Juan M. Ortigueira,a   Jesús J. Fernández,b   Harry Adams,c   M. Teresa Pereira*a  and  José M. Vila*a  

* Corresponding authors

a Departamento de Química Inorgánica, Universidade de Santiago de Compostela, Avenida das Ciencias s/n, 15782 Santiago de Compostela, Spain
E-mail: josemanuel.vila@usc.es

b Departamento de Química Fundamental and Centro de Investigacións Científicas Avanzadas (CICA), Facultade de Ciencias, Universidade da Coruña, E-15071 A Coruña, Spain

c Department of Chemistry, The University, Sheffield S3 7HF, UK

Abstract

Herein we report a Suzuki–Miyaura type cross-coupling between an aryl halide and a functionalized boronic acid palladacycle in the absence of an external catalyst. This reaction is an unprecedented case of catalysis in palladium metallacycle chemistry.

Graphical abstract: Palladacycle catalysis: an innovation to the Suzuki–Miyaura cross-coupling reaction

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Article information

DOI
https://doi.org/10.1039/C6DT03542F
Article type
Communication
Submitted
11 Sep 2016
Accepted
18 Oct 2016
First published
18 Oct 2016

Dalton Trans., 2016,45, 17598-17601

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Palladacycle catalysis: an innovation to the Suzuki–Miyaura cross-coupling reaction

F. Lucio-Martínez, L. A. Adrio, P. Polo-Ces, J. M. Ortigueira, J. J. Fernández, H. Adams, M. T. Pereira and J. M. Vila, Dalton Trans., 2016, 45, 17598 DOI: 10.1039/C6DT03542F

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