Issue 43, 2019
From the journal:

RSC Advances

Methods for direct C(sp2)–H bonds azidation

Ying Liu,a   Abdol Ghaffar Ebadi,b   Leila Youseftabar-Miri,c   Akbar Hassanpourd  and  Esmail Vessally ORCID logo *e  

* Corresponding authors

a College of Science, North China University of Science and Technology, Tangshan 063210, China

b Department of Agriculture, Jouybar Branch, Islamic Azad University, Jouybar, Iran

c Department of Organic Chemistry, Faculty of Pharmaceutical Chemistry, Tehran Medical Sciences, Islamic Azad University, Tehran, Iran

d Department of Chemistry, Marand Branch, Islamic Azad University, Marand, Iran

e Department of Chemistry, Payame Noor University, Tehran, Iran
E-mail: vessally@yahoo.com

Abstract

Direct functionalization of C–H bonds has attracted great attention in recent years from the perspectives of atom and step economy. In this context, a variety of processes have been developed for the construction of synthetically and biologically important organic azides through the oxidative C–H bonds azidation. In this review, we have summarized recent progress in the direct azidation of C(sp2)–H bonds. The review is divided into three major sections: (i) direct azidation of aromatic C–H bonds; (ii) direct azidation of olefinic C–H bonds; and (iii) direct azidation of aldehydic C–H bonds. Mechanistic aspects of the reactions are considered and discussed in detail.

Graphical abstract: Methods for direct C(sp2)–H bonds azidation

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Article information

DOI
https://doi.org/10.1039/C9RA04534A
Article type
Review Article
Submitted
17 Jun 2019
Accepted
30 Jul 2019
First published
13 Aug 2019
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2019,9, 25199-25215

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Methods for direct C(sp2)–H bonds azidation

Y. Liu, A. G. Ebadi, L. Youseftabar-Miri, A. Hassanpour and E. Vessally, RSC Adv., 2019, 9, 25199 DOI: 10.1039/C9RA04534A

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