The new pentaruthenium phenylphosphidoanthracene bow-tie cluster, [Ru5(CO)13(µ5-η1 : η2 : η3 : η3-C14H8-η1- PPh)], is prepared from the thermolysis of [Ru3(CO)12] and (9-anthracyl)diphenylphosphine, the crystal structure of which reveals a unique µ5-interaction of the ligand with the ruthenium cluster.
A. J. Deeming and C. M. Martin, Chem. Commun., 1996, 53 DOI: 10.1039/CC9960000053
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