Issue 4, 1996
From the journal:

Chemical Communications

Experimental determination of the electron configuration of the nickel ion in a complexed macrocycle by X-ray diffraction

Garry T. Smith,   Paul R. Mallinson,   Robert D. Peacock,   Louis J. Farrugia,   Ian A. Fallis,   Christopher S. Frampton  and  Judith A. K. Howard  

Abstract

The results of a multipole analysis with high-resolution X-ray diffraction data for [Ni(H3L)][NO3][PF6][H3L[double bond, length half m-dash]N,N′,N″-tris(2-hydroxy-3-methylbutyl)-1,4,7-triazacyclononane], to determine the electron configuration in the C3 symmetry-adapted orbiatals of the Ni ion, are consistent with higher occupancy of the crystal-field stabilized e(t2g) orbitals relative to the destabilized e(eg) pair, suggesting a predominantly ionic metal–ligand interaction.

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Article information

DOI
https://doi.org/10.1039/CC9960000525
Article type
Paper

Chem. Commun., 1996, 525-526

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Experimental determination of the electron configuration of the nickel ion in a complexed macrocycle by X-ray diffraction

G. T. Smith, P. R. Mallinson, R. D. Peacock, L. J. Farrugia, I. A. Fallis, C. S. Frampton and J. A. K. Howard, Chem. Commun., 1996, 525 DOI: 10.1039/CC9960000525

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