The silylene–borane adduct 2 is formed from the corresponding silylene and tris(pentafluorophenyl)borane and rearranges to silylborane 3 with a half-life of about one month in toluene.
N. Metzler and M. Denk, Chem. Commun., 1996, 2657 DOI: 10.1039/CC9960002657
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