Issue 66, 2020
From the journal:

Chemical Communications

A remarkably air-stable quinodimethane radical cation†

Mei Harada,‡a   Masaru Tanioka, ORCID logo ‡ab   Atsuya Muranaka, ORCID logo *c   Tetsuya Aoyama,c   Shinichiro Kamino ORCID logo b  and  Masanobu Uchiyama ORCID logo *acd  

* Corresponding authors

a Graduate School of Pharmaceutical Sciences, The University of Tokyo, Tokyo 113-0033, Japan
E-mail: uchiyama@mol.f.u-tokyo.ac.jp

b School of Pharmaceutical Sciences, Aichi Gakuin University, Aichi 464-8650, Japan

c Cluster of Pioneering Research (CPR), Advanced Elements Chemistry Laboratory, RIKEN, Saitama, Japan
E-mail: atsuya-muranaka@riken.jp

d Research Initiative for Supra-Materials (RISM), Shinshu University, 3-15-1 Tokida, Ueda, Nagano 386-8567, Japan

Abstract

An ambient-stable radical cation of a Thiele's hydrocarbon derivative has been synthesized and its properties have been explored using a combined experimental and computational approach. The radical cation exhibited several intense near-infrared absorption bands and its solution-processed thin films showed high electrical conductivity at room temperature.

Graphical abstract: A remarkably air-stable quinodimethane radical cation

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Article information

DOI
https://doi.org/10.1039/D0CC04025H
Article type
Communication
Submitted
09 Jun 2020
Accepted
10 Jul 2020
First published
11 Jul 2020

Chem. Commun., 2020,56, 9565-9568

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A remarkably air-stable quinodimethane radical cation

M. Harada, M. Tanioka, A. Muranaka, T. Aoyama, S. Kamino and M. Uchiyama, Chem. Commun., 2020, 56, 9565 DOI: 10.1039/D0CC04025H

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