Issue 9, 2020

Magnetic In–Pd catalysts for nitrate degradation

Abstract

Magnetic catalysts offer the possibility of rapidly eliminating nitrate oxyanions, a ubiquitous drinking water contaminant, without generating a secondary waste stream. Herein, we report the synthesis of a magnetically recoverable bimetallic Pd–In material that exhibits excellent chemical stability, reusability, and high nitrate removal efficiency. This four-component catalyst (Pd–In/nFe3O4@SiO2) contains nanocrystalline magnetite with a silica shell upon which indium-decorated palladium nanoparticles attach. The SiO2 shell slowed down iron leaching from Fe3O4 and the bimetallic nano-domains showed nitrate reduction activity in deionized water without obvious deactivation through multiple recovery and reuse cycles. This magnetically responsive, reusable catalyst, which retained activity in simulated drinking water, can serve as a design basis for materials to degrade other oxyanion water contaminants.

Graphical abstract: Magnetic In–Pd catalysts for nitrate degradation

Supplementary files

Article information

Article type
Paper
Submitted
16 Jan 2020
Accepted
17 Aug 2020
First published
18 Aug 2020

Environ. Sci.: Nano, 2020,7, 2681-2690

Author version available

Magnetic In–Pd catalysts for nitrate degradation

S. Guo, C. D. Powell, D. Villagrán and M. S. Wong, Environ. Sci.: Nano, 2020, 7, 2681 DOI: 10.1039/D0EN00069H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements