Volume 79, 1985

A model for domain flow of liquid-crystal polymers

Abstract

Liquid-crystal polymers often exhibit a low-shear-rate region of shear thinning of viscosity, accompanied by lack of net orientation and by a dependence of texture and rheology on shear history. A phenomenological model to account for this region is presented. The model uses Marrucci's description of stable domains whose size is a function of stress. The interaction of these domains is estimated from the continuum theory of liquid crystals. The shear-rate-dependent viscosity and normal stress of the polydomain fluid are calculated from the interaction energy and size of the domain by analogy with non-equilibrium molecular-dynamics calculations for small-molecule fluids. The shear-rate dependences are similar to those observed experimentally. Other tests of the model, including optical observations and measurement of dynamic viscosity, are proposed.

Article information

Article type
Paper

Faraday Discuss. Chem. Soc., 1985,79, 161-173

A model for domain flow of liquid-crystal polymers

K. F. Wissbrun, Faraday Discuss. Chem. Soc., 1985, 79, 161 DOI: 10.1039/DC9857900161

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