Issue 2, 1972
From the journal:

Journal of the Chemical Society, Dalton Transactions

Kinetics of substitution at bis(2,2′-bipyridyl)biscyanoiron(II)

J. Burgess  

Abstract

The kinetics of reaction of Fe(bipy)2(CN)2 with 1,10-phenanthroline have been investigated in water and in mixed aqueous solvents. Logarithms of rate constants for this reaction, and for the analogous reaction of a Schiff base complex Fe(SB)2(CN)2, where SB =N-(2-pyridylmethylene)-3,4-dimethylaniline, correlate linearly with Grunwald–Winstein solvent Y values. Reaction of Fe(bipy)2(CN)2 with hydroxide follows a first-order rate law with rates independent of hydroxide concentration.

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Article information

DOI
https://doi.org/10.1039/DT9720000203
Article type
Paper

J. Chem. Soc., Dalton Trans., 1972, 203-206

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Kinetics of substitution at bis(2,2′-bipyridyl)biscyanoiron(II)

J. Burgess, J. Chem. Soc., Dalton Trans., 1972, 203 DOI: 10.1039/DT9720000203

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