Issue 5, 1972
From the journal:

Journal of the Chemical Society, Dalton Transactions

Molybdenum(IV) oxo-complexes. Part II. Crystal and molecular structure of dichlorotris(diethylphenylphosphine)oxomolybdenum(IV), cis-mer-[MoOCl2(PEt2Ph)3]

Ljubica Manojlović-Muir  and  Kenneth W. Muir  

Abstract

The molecular geometry of the title compound has been determined by X-ray crystal-structure analysis from diffractometer data. The crystals are monoclinic, space-group P21/c, a= 12·238(6), b= 14·818(10), c= 21·687(10)Å, β= 121·28(3)°, Z= 4. The structure was solved by the heavy-atom method and refined by full-matrix least-squares to R 0·081 for 2283 reflections.

The crystals are built of monomeric molecular units, with distorted octahedral co-ordination around the molybdenum atom. The molybdenum–ligand bond distances are: Mo–O 1·801(9), Mo–Cl (trans to O) 2·424(4), Mo–Cl (trans to P) 2·482(4), Mo–P (trans to Cl) 2·522(4), and Mo–P (trans to P) 2·580(5) and 2·553(5)Å.

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Article information

DOI
https://doi.org/10.1039/DT9720000686
Article type
Paper

J. Chem. Soc., Dalton Trans., 1972, 686-690

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Molybdenum(IV) oxo-complexes. Part II. Crystal and molecular structure of dichlorotris(diethylphenylphosphine)oxomolybdenum(IV), cis-mer-[MoOCl2(PEt2Ph)3]

L. Manojlović-Muir and K. W. Muir, J. Chem. Soc., Dalton Trans., 1972, 686 DOI: 10.1039/DT9720000686

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