Issue 19, 1972
From the journal:

Journal of the Chemical Society, Dalton Transactions

Chemistry of the metal carbonyls. Part LXV. Reactions between dodecacarbonyltriruthenium and tertiary phosphines or arsines

M. I. Bruce,   G. Shaw  and  F. G. A. Stone  

Abstract

The preparation of trinuclear ruthenium complexes of the type Ru3(CO)12 –nLn(L = tertiary phosphine or arsine; n= 1–4) is described. Their i.r. and 1H n.m.r. spectra are discussed and possible structures suggested.

The complexes Ru3(CO)9L3[L = PPh3, P(m-C6H4Me)3, P(p-C6H4Me)3 or PMePh2] undergo controlled pyrolytic reactions in boiling decalin, affording complexes of the type Ru2(CO)6(PAr2)2(Ar = Ph or m-MeC6H4),Ru2(CO)6[PPhR(C6H4)](PPhR)(R = Ph or Me), Ru2(CO)6[PPh2(C6H4)]2, and Ru3(CO)7(PAr3)(PAr2)(Ar = Ph, m-MeC6H4, or p-MeC6H4). Spectroscopic data suggest structures containing bridging phosphido-ligands, and ortho-metallated phenyl rings.

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Article information

DOI
https://doi.org/10.1039/DT9720002094
Article type
Paper

J. Chem. Soc., Dalton Trans., 1972, 2094-2099

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Chemistry of the metal carbonyls. Part LXV. Reactions between dodecacarbonyltriruthenium and tertiary phosphines or arsines

M. I. Bruce, G. Shaw and F. G. A. Stone, J. Chem. Soc., Dalton Trans., 1972, 2094 DOI: 10.1039/DT9720002094

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