Trimethylsilylmethyl (R) complexes R2[graphic omitted]SiMe3(M = Nb and Ta) and neopentyl (R′) complexes, MR′4(M = Ti andZr), R′3TaCl2 and Mo2R′6 are obtained by the interaction of Grignard or lithium reagents derived from chloromethyltrimethylsilane and neopentyl chloride with the appropriate metal halide 1H N.m.r. and i.r. spectra are reported.
W. Mowat and G. Wilkinson, J. Chem. Soc., Dalton Trans., 1973, 1120 DOI: 10.1039/DT9730001120
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