Issue 20, 1973
From the journal:

Journal of the Chemical Society, Dalton Transactions

Arene–molybdenum chemistry: nucleophilic addition to the cations [C6H6Mo(π-C3H5)L2]+ giving cyclohexadienyl derivatives

Malcolm L. H. Green,   Leonard C. Mitchard  and  William E. Silverthorn  

Abstract

The dimer [C6H6Mo(π-C3H6)Cl]2 is cleaved by chelate ligands L2 giving the cations [C6H6Mo(π-C3H5)L2]+[L2= Ph2PCH2CH2PPh2(dppe), Me2PCH2CH2PMe2(dmpe), or (MeSCH2)2]. The cations react with nucleophiles (R–= H–, Bun, and, when L2= dppe, CN–) giving the neutral cyclohexadienyl derivatives [(C6H6R)Mo(π-C3H5)L2]. An asymmetric structure for the latter is suggested by 1H n.m.r. spectra at 270 MHz and double-resonance experiments. The cations [(C6H6R′)Mo(π-C3H5)L2′]+, (R′= H or Me, L2′= en, bipy, and o-phenylenediamine) are also described.

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Article information

DOI
https://doi.org/10.1039/DT9730002177
Article type
Paper

J. Chem. Soc., Dalton Trans., 1973, 2177-2182

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Arene–molybdenum chemistry: nucleophilic addition to the cations [C6H6Mo(π-C3H5)L2]+ giving cyclohexadienyl derivatives

M. L. H. Green, L. C. Mitchard and W. E. Silverthorn, J. Chem. Soc., Dalton Trans., 1973, 2177 DOI: 10.1039/DT9730002177

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