Issue 5, 1974

Pyrazolyl derivatives of aluminium and gallium

Abstract

A series of volatile, tricyclic derivatives, [ N2C3H3·MR2]2(where M = Al or Ga; R = H, D, Me, Et, or Cl) has been synthesised by reacting pyrazole with the appropriate aluminium or gallium precursor. The resulting dimeric compounds have been characterised by elemental analyses, molecular weight determinations, and by 1H n.m.r. and mass spectroscopic measurements. In all cases a boat conformation for the six-membered ring of four nitrogen and two metal atoms is consistent with the experimental results.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1974, 503-506

Pyrazolyl derivatives of aluminium and gallium

A. Arduini and A. Storr, J. Chem. Soc., Dalton Trans., 1974, 503 DOI: 10.1039/DT9740000503

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