Issue 20, 1974
From the journal:

Journal of the Chemical Society, Dalton Transactions

Reactions of lithium nitride with cerium, thorium, and hafnium: formation of Li2CeN2, Ce2N2O, Li2ThN2, and Li2HfN2

Marten G. Barker  and  Iain C. Alexander  

Abstract

The solid-state reactions of lithium nitride with Ce, Th, Hf and CeN, ThN, and HfN have been followed by differential thermal analysis, thermogravimetric analysis, and X-ray powder diffraction methods. Reaction with the metals was found to proceed by formation of the mononitride with the ternary nitride Li2MN2 as the final product. The compound Ce2N2O was obtained by the reaction of Li2CeN2 and Li2O or CeN and CeO2. The reaction of lithium nitride with hafnium gave the ternary nitride Li2HfN2 which is found to be isostructural with the known nitride Li2ZrN2.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/DT9740002166
Article type
Paper

J. Chem. Soc., Dalton Trans., 1974, 2166-2170

Permissions

Request permissions

Reactions of lithium nitride with cerium, thorium, and hafnium: formation of Li2CeN2, Ce2N2O, Li2ThN2, and Li2HfN2

M. G. Barker and I. C. Alexander, J. Chem. Soc., Dalton Trans., 1974, 2166 DOI: 10.1039/DT9740002166

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements