Issue 15, 1975
From the journal:

Journal of the Chemical Society, Dalton Transactions

Kinetic and equilibrium studies on iron(II) and iron(III) pentacyanoferrates

Alan D. James  and  Robin S. Murray  

Abstract

The results of a kinetic investigation of the reaction of [FeII(CN)5(py)]3–(py = pyridine) with CN– and HCN are reported, together with a linear free-energy treatment of data obtained for aquation reactions of species of the type [FeII(CN)5X](X = an uncharged or univalent anion). Equilibrium studies of [FeII(CN)5OH2]3– and [FeIII(CN)5OH2]2– with a number of substituents have confirmed the class (b) or ‘soft’ character of the iron centre in these complexes.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/DT9750001530
Article type
Paper

J. Chem. Soc., Dalton Trans., 1975, 1530-1533

Permissions

Request permissions

Kinetic and equilibrium studies on iron(II) and iron(III) pentacyanoferrates

A. D. James and R. S. Murray, J. Chem. Soc., Dalton Trans., 1975, 1530 DOI: 10.1039/DT9750001530

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements