Issue 14, 1976
From the journal:

Journal of the Chemical Society, Dalton Transactions

Crystal structures of silver dimolybdate, Ag2Mo2O7, and silver ditungstate, Ag2W2O7

Bryan M. Gatehouse  and  Peter Leverett  

Abstract

The crystal structures of Ag2Mo2O7(I) and Ag2W2O7(II) have been determined by single-crystal X-ray analysis. Both compounds crystallize in space group P[1 with combining macron], Z= 2, with for (I): a= 6.095(3), b= 7.501(3), c= 7.681(3)Å, α= 110.4(1), β= 93.3(1), γ= 113.5(1)°; and for (II): a = 6.033(3), b= 7.051 (3), c= 7.735(3)Å, α= 73.8(1), β= 92.2(1), γ= 104.7(1)°. The structures were determined from diffractometer data by heavy-atom methods and refined to R 0.045 [(I), 1 208 observed reflections] and 0.047 [(II), 1 364 observed reflections]. The structures consist of infinite chains formed by blocks of four edge-shared octahedra joined by edge-sharing in (I), and by corner-sharing in (II), with the silver ions situated between the chains.

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Article information

DOI
https://doi.org/10.1039/DT9760001316
Article type
Paper

J. Chem. Soc., Dalton Trans., 1976, 1316-1320

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Crystal structures of silver dimolybdate, Ag2Mo2O7, and silver ditungstate, Ag2W2O7

B. M. Gatehouse and P. Leverett, J. Chem. Soc., Dalton Trans., 1976, 1316 DOI: 10.1039/DT9760001316

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