Issue 14, 1976
From the journal:

Journal of the Chemical Society, Dalton Transactions

Thermodynamic considerations in co-ordination. Part XXV. Formation of ternary complexes containing two dissimilar metal ions and the implication for metal–metal stimulation phenomena in viva

Murray L. D. Touche  and  David R. Williams  

Abstract

Potentiometric studies are reported for calcium(II), lanthanum(III), and zinc(II) binary complexes and for calcium(II) and zinc(II) or lanthanum(III) and zinc(II) ternary complexes of glutathionate at 37 °C and 0.15 10–3 mol dm–3(Na+)[ClO4]. Formation constants have been computed and used to calculate the concentrations of the complexes at various pH. Both calcium and lanthanum ions encourage the formation of neutral membrane-permeable complexes of zinc ions and the systems are used to discuss the principles of metal–metal stimulation phenomena in viva.

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Article information

DOI
https://doi.org/10.1039/DT9760001355
Article type
Paper

J. Chem. Soc., Dalton Trans., 1976, 1355-1359

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Thermodynamic considerations in co-ordination. Part XXV. Formation of ternary complexes containing two dissimilar metal ions and the implication for metal–metal stimulation phenomena in viva

M. L. D. Touche and D. R. Williams, J. Chem. Soc., Dalton Trans., 1976, 1355 DOI: 10.1039/DT9760001355

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