Issue 21, 1976
From the journal:

Journal of the Chemical Society, Dalton Transactions

Acetates and acetato-complexes. Part 2. Spectroscopic studies

Nathaniel W. Alcock,   Valerie M. Tracy  and  Thomas C. Waddington  

Abstract

The effect of different modes of co-ordination on the i.r. spectrum of the acetate ion is reviewed. Infrared and 1H n.m.r. spectra of a series of metal acetates and acetato-complexes are reported. and the type of co-ordination identified: B2O(O2CMe)4 and Na[B2O(O2CMe)5] contain both bridging and unidentate acetate; Al(O2CMe)3 probably contains bridging acetate only: Si(O2CMe)4, Ge(O2CMe)4, K2[Si(O2CMe)6], and K2[Ge(O2CMe)5] contain only unidentate acetate: Zr(O2CMe)4 and Pb(O2CMe)4 contain only chelating acetate: K2[Sn(O2CMe)6], K2[Pb(O2CMe)6], and [NMe4][Sn(OMe)5] contain both chelating and unidentate acetate; and Sn(O2CMe)4 contains symmetrical and unsymmetrical chelating acetate.

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Article information

DOI
https://doi.org/10.1039/DT9760002243
Article type
Paper

J. Chem. Soc., Dalton Trans., 1976, 2243-2246

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Acetates and acetato-complexes. Part 2. Spectroscopic studies

N. W. Alcock, V. M. Tracy and T. C. Waddington, J. Chem. Soc., Dalton Trans., 1976, 2243 DOI: 10.1039/DT9760002243

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