Issue 8, 1978
From the journal:

Journal of the Chemical Society, Dalton Transactions

Reactions of low-spin iron(II) complexes with hydroxide ion in aqueous methanol: the effect of ligand on rates of reaction

Michael J. Blandamer,   John Burgess,   Peter Cookson,   David L. Roberts,   Paul Wellings,   Fikry M. Mekhail  and  Pakinam Askalani  

Abstract

Rate laws and rate constants are reported for reactions of several low-spin iron(II) complexes with hydroxide ion in methanol-water solutions. The dependence of the form of the rate law and of reactivity on ligand type and on substituent nature is discussed. The pattern of reactivity for a range of compounds with hydroxide ion in methanol-water mixtures is compared with the reactivity pattern for analogous reactions in dimethyl sulphoxide-water mixtures.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/DT9780000996
Article type
Paper

J. Chem. Soc., Dalton Trans., 1978, 996-1000

Permissions

Request permissions

Reactions of low-spin iron(II) complexes with hydroxide ion in aqueous methanol: the effect of ligand on rates of reaction

M. J. Blandamer, J. Burgess, P. Cookson, D. L. Roberts, P. Wellings, F. M. Mekhail and P. Askalani, J. Chem. Soc., Dalton Trans., 1978, 996 DOI: 10.1039/DT9780000996

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements