Issue 2, 1979
From the journal:

Journal of the Chemical Society, Dalton Transactions

Some chemistry of ethyltetramethylcyclopentadienylcobalt: arene, ethylene, butadiene, ammine, tertiary phosphine, and chloro-derivatives

Malcolm L. H. Green  and  Richard B. A. Pardy  

Abstract

Tri-n-butyl(ethyltetramethylcyclopentadienyl)tin, Sn(etmcp)Bun3, reacts with cobalt(II) chloride to give, after treatment with chlorine, [{Co(etmcp)Cl(µ-Cl)}2] and [Co3(etmcp)2Cl6]. Using these compounds as precursors, many derivatives of the Co(η-etmcp) system have been prepared; examples are [(η-etmcp)Co(µ-Cl)3Co(η-etmcp)][FeCl4], [Co(η-etmcp)(PPh3)Cl2], [Co(η-etmcp)L2Cl][PF6][L2= Ph2P(CH2)2PPh2, or (PMe2Ph)2], [Co(η-etmcp)L3][PF6][L3=(NH3)3, (MeCN)3, (MeCN)2(Me2C[double bond, length as m-dash]NH), (CH2[double bond, length half m-dash]CHCN)3, η-benzene, or η-toluene], and [Co(η-etmcp)L2][L2=(η-C2H4)2, butadiene, or 1,5-C8H12].

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Article information

DOI
https://doi.org/10.1039/DT9790000355
Article type
Paper

J. Chem. Soc., Dalton Trans., 1979, 355-360

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Some chemistry of ethyltetramethylcyclopentadienylcobalt: arene, ethylene, butadiene, ammine, tertiary phosphine, and chloro-derivatives

M. L. H. Green and R. B. A. Pardy, J. Chem. Soc., Dalton Trans., 1979, 355 DOI: 10.1039/DT9790000355

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