Hydrolysis of titanium(IV) has been studied in 2.0 mol dm–3 aqueous (Na,H)Cl solution at 25 °C by means of e.m.f. measurements of a cell containing 0.019 3–0.048 2 mol dm–3 titanium(IV). Titanium(IV), which is present in the form of titanyl ion, [TiO]2+, is partially hydrolyzed to form a polynuclear cationic complex, [(TiO)8(OH)12]4+(log β8,12=–1.68± 0.10).
H. Einaga, J. Chem. Soc., Dalton Trans., 1979, 1917 DOI: 10.1039/DT9790001917
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