Issue 9, 1988
From the journal:

Journal of the Chemical Society, Dalton Transactions

The first complexes of cyanogen halides with silver(I): crystal structure of [Ag(NCCl)2][SbF6]

Herbert W. Roesky,   Jürgen Schimkowiak,   Peter G. Jones,   Mathias Noltemeyer  and  George M. Sheldrick  

Abstract

The reactions of Ag[AsF6] or Ag[SbF6] with ClCN, BrCN, and ICN yield the complexes [Ag(NCCl)2][AsF6], [Ag(NCCl)2][SbF6], [Ag(NCBr)2][AsF6], [Ag(NCBr)2][SbF6], and [Ag(NCl)2][AsF6]. The salt [Ag(NCCl)2][SbF6] was characterized by an X-ray single-crystal structure investigation. The cation is monomeric. The cyanogen halide is bonded to the silver through nitrogen, with Ag–N 2.140(4)Å. The co-ordination geometry at silver is exactly linear.

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Article information

DOI
https://doi.org/10.1039/DT9880002507
Article type
Paper

J. Chem. Soc., Dalton Trans., 1988, 2507-2508

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The first complexes of cyanogen halides with silver(I): crystal structure of [Ag(NCCl)2][SbF6]

H. W. Roesky, J. Schimkowiak, P. G. Jones, M. Noltemeyer and G. M. Sheldrick, J. Chem. Soc., Dalton Trans., 1988, 2507 DOI: 10.1039/DT9880002507

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