Issue 23, 1992
From the journal:

Journal of the Chemical Society, Dalton Transactions

Synthesis and electrochemistry of [{Mo(NO)[HB(3,5-Me2C3HN2)3]Cl}2{1,2-(NH)2C6H4}] and the crystal structure of [{Mo(NO)[HB(3,5-Me2C3HN2)3]I}2{1,2-(NH)2C6H4}]

Najat J. AlObaidi,   Sean L. W. McWhinnie,   Thomas A. Hamor,   Christopher J. Jones  and  Jon A. McCleverty  

Abstract

Cyclic voltammetry of the 1,2-phenylenediamide-bridged bimetallic complex [{Mo(NO)L(Cl)}2{1,2-(NH)2C6H4}][L = HB(3,5-Me2C3HN2)3] has revealed two one-electron reduction processes separated by 770 mV, a value which is in accord with the presence of strongly interacting molybdenum centres but intermediate between those found for the corresponding complexes containing 1,4- and 1,3-disubstituted aryl bridging groups. The crystal structure of [{Mo(NO)L(I)}2{1,2-(NH)2C6H4}] has been determined. It contains Mo–N(arylamide) distances of 1.957(6)Å and reveals a non-planar structure for the MoN(amide)–C–C–N(amide)Mo moiety which may account for the lower than expected Mo ⋯ Mo interaction detected electrochemically.

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Article information

DOI
https://doi.org/10.1039/DT9920003299
Article type
Paper

J. Chem. Soc., Dalton Trans., 1992, 3299-3302

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Synthesis and electrochemistry of [{Mo(NO)[HB(3,5-Me2C3HN2)3]Cl}2{1,2-(NH)2C6H4}] and the crystal structure of [{Mo(NO)[HB(3,5-Me2C3HN2)3]I}2{1,2-(NH)2C6H4}]

N. J. AlObaidi, S. L. W. McWhinnie, T. A. Hamor, C. J. Jones and J. A. McCleverty, J. Chem. Soc., Dalton Trans., 1992, 3299 DOI: 10.1039/DT9920003299

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